I would just be very professional and courteous. Indicate that you are very interested in attending their law school, but that you had a couple of questions that you would like to discuss with the professor prior to committing.
Of course, you should research the school thoroughly before the call, especially paying close attention to the curriculum offered and other publicly available information via their website, in the effort to ask pointed, meaningful and intelligent questions. If you attend, you may deal with the professor in some capacity.