It's hard to say, they're both have similar rankings.
But from a geographic standpoint, I would give the edge to Syracuse simply because their alumni base is huge and many are from the NYC area. If you want to do law, NYC ain't a bad place to practice. But in NYC, you're competing with the T14 students and the local NYC schools, so I'm not sure how well Syracuse grads do in NYC. Agian, I would suspect that the Syracuse grad would do a little better than the Penn State grad if you want to practice in NY. Vice versa if you wanted to practice in Philly. Good luck!